{"id":24872,"date":"2022-03-16T09:19:39","date_gmt":"2022-03-16T08:19:39","guid":{"rendered":"https:\/\/stage.muegge.de\/empowering-zero-emission-duo-plasmaline-driving-performance-and-efficiency-of-fuel-cells\/"},"modified":"2022-03-16T09:31:13","modified_gmt":"2022-03-16T08:31:13","slug":"empowering-zero-emission-duo-plasmaline-driving-performance-and-efficiency-of-fuel-cells","status":"publish","type":"post","link":"https:\/\/muegge-group.com\/fr\/empowering-zero-emission-duo-plasmaline-driving-performance-and-efficiency-of-fuel-cells\/","title":{"rendered":"Pour une \u00e9mission z\u00e9ro: Duo-Plasmaline au service de la performance et de l\u00b4efficacit\u00e9 des piles \u00e0 combustible"},"content":{"rendered":"\t\t
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Comment la technologie plasma micro-ondes r\u00e9sout le probl\u00e8me de d\u00e9gradation de performance des piles \u00e0 combustible ?<\/h2>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
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Les piles \u00e0 combustible bas\u00e9es sur des membranes ionom\u00e8res sont tr\u00e8s importantes, par exemple pour les v\u00e9hicules \u00e0 faible \/ z\u00e9ro \u00e9mission. Le principal inconv\u00e9nient des membranes ionom\u00e8res comme le Nafion dans les piles \u00e0 combustible \u00e0 m\u00e9thanol direct (DMFC) \u2013 Figure 8 – est que la conductivit\u00e9 ionique du Nafion augmente avec le niveau d’hydratation\u00a0; leur perm\u00e9abilit\u00e9 relativement importante au m\u00e9thanol entra\u00eene une d\u00e9gradation radicale du rendement de la pile \u00e0 combustible. \u00a0Le traitement de surface par plasma micro-ondes de ces membranes peut r\u00e9duire la perm\u00e9abilit\u00e9 au m\u00e9thanol. De plus, la force de liaison de la membrane au catalyseur peut \u00eatre am\u00e9lior\u00e9e par le traitement de surface par plasma.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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Figure 1 : Sch\u00e9ma d’une pile \u00e0 combustible \u00e0 m\u00e9thanol directe (DFMC) [8-9].<\/p>

\u00a0<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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La technologie du plasma pour am\u00e9liorer les probl\u00e8mes de gestion de l'eau<\/h4>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t
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La couche poreuse de diffusion de gaz (GDL) est un autre composant important d’une pile \u00e0 combustible. Elle fournit un flux de gaz homog\u00e8ne au catalyseur et contr\u00f4le la teneur en eau de la pile. En particulier, la gestion de l’eau sur une large gamme de courbes de polarisation tension \/ courant est tr\u00e8s importante pour l’efficacit\u00e9 de la pile. Cependant, les GDLs sont g\u00e9n\u00e9ralement constitu\u00e9s d’un mat\u00e9riau fortement hydrophobe, ce qui est essentiel pour une bonne gestion de l’eau. Une GDL partiellement hydrophile est pourtant un meilleur choix, car elle peut ainsi retenir une quantit\u00e9 optimis\u00e9e d’eau, ce qui m\u00e8ne \u00e0 un meilleur rendement de la pile \u00e0 combustible.<\/p>

\u00a0<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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Figure 2 : Surface \u00e0 l’origine totalement hydrophobe d’une couche de diffusion de gaz (GDL), pr\u00e9sentant des propri\u00e9t\u00e9s hydrophiles sur les zones expos\u00e9es au plasma vs. gouttelettes d’eau adh\u00e9rant \u00e0 ces zones hydrophiles apr\u00e8s le traitement par plasma micro-ondes \u00e0 basse pression [9-10].<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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Les propri\u00e9t\u00e9s partiellement hydrophiles de la GDL peuvent \u00eatre obtenues, par exemple, par un traitement de surface de la GDL par un plasma d’azote. Lorsque la GDL est recouverte d’une plaque perfor\u00e9e, seules les zones non couvertes de la surface de la GDL sont modifi\u00e9es par le traitement plasma. Par cons\u00e9quent, les zones non couvertes de la surface de la GDL pr\u00e9sentent des propri\u00e9t\u00e9s hydrophiles apr\u00e8s le traitement par plasma (gouttelettes d’eau adh\u00e9rant \u00e0 ces zones dans la Figure 2), tandis que les zones couvertes (non expos\u00e9es au plasma) de la GDL conservent leurs propri\u00e9t\u00e9s hydrophiles initiales.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

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Des r\u00e9sultats prouv\u00e9s : Des piles \u00e0 combustible plus performantes<\/h4>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t
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La pile \u00e0 combustible avec la GDL trait\u00e9e par plasma micro-ondes pr\u00e9sente des tensions de cellule nettement plus \u00e9lev\u00e9es que la pile \u00e0 combustible de r\u00e9f\u00e9rence sans GDL trait\u00e9 par plasma. Cela est d\u00fb au fait que la membrane d’une pile \u00e0 combustible sans GDL trait\u00e9 par plasma s’ass\u00e8che, en particulier \u00e0 des densit\u00e9s de courant plus \u00e9lev\u00e9es. En utilisant une GDL trait\u00e9e par plasma, une certaine quantit\u00e9 d’eau peut \u00eatre retenue dans la pile, ce qui am\u00e9liore les performances de la pile \u00e0 combustible.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t

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La technologie plasma peut renforcer vos performances de nombreuses fa\u00e7ons. Contactez-nous pour d\u00e9couvrir comment nous pouvons personnaliser ou standardiser nos syst\u00e8mes pour r\u00e9pondre \u00e0 vos d\u00e9fis \u2013 faites-nous part de vos innovations, projets et activit\u00e9s.<\/h4>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
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\u00a0<\/strong><\/p>

\u00a0<\/strong><\/p>

Bibliographie<\/strong>:<\/p>

[1]\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 M. Walker, K.-M. Baumg\u00e4rtner, M. Kaiser, J. Kerres, A. Ullrich, E. R\u00e4uchle, J. Appl. Polym. Sci.<\/em>, 1999, 74, 67-73.<\/p>

[2]\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 M. Walker: Fuel Cells. [online] Homepage: University of Stuttgart, Institute of Interfacial Process Engineering and Plasma Technology (IGVP)<\/p>

URL: https:\/\/www.igvp.uni-stuttgart.de\/en\/research\/plasma-technology\/processes\/fuel-cells\/<\/a> [status: June 16, 2021].<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"

Comment la technologie plasma micro-ondes r\u00e9sout le probl\u00e8me de d\u00e9gradation de performance des piles \u00e0 combustible ? Les piles \u00e0 combustible bas\u00e9es sur des membranes ionom\u00e8res sont tr\u00e8s importantes, par exemple pour les v\u00e9hicules \u00e0 faible \/ z\u00e9ro \u00e9mission. Le principal inconv\u00e9nient des membranes ionom\u00e8res comme le Nafion dans les piles \u00e0 combustible \u00e0 m\u00e9thanol […]<\/p>\n","protected":false},"author":4,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[5347,4450],"tags":[6543,6103,6104,6544,6545],"class_list":["post-24872","post","type-post","status-publish","format-standard","hentry","category-power-to-x-applications-en-fr","category-technologie-micro-ondes","tag-dou-plasmaline-fr","tag-microwaves-fr","tag-mikrowelle-en-fr","tag-muegge-blog-en-fr","tag-plasma-fr"],"acf":[],"yoast_head":"\nPour une \u00e9mission z\u00e9ro: Duo-Plasmaline au service de la performance et de l\u00b4efficacit\u00e9 des piles \u00e0 combustible - Muegge<\/title>\n<meta name=\"description\" content=\"How Duo-Plasmaline systems open new horizons for growing marketsHow plasma technology solves the challenge of performance degradation in fuel cells\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/muegge-group.com\/fr\/empowering-zero-emission-duo-plasmaline-driving-performance-and-efficiency-of-fuel-cells\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Pour une \u00e9mission z\u00e9ro: Duo-Plasmaline au service de la performance et de l\u00b4efficacit\u00e9 des piles \u00e0 combustible - 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